J.C. Moore Online

Current Events from a Science Perspective

There’s a little bit of truth to every myth, and the hydrogen economy is no different. Hydrogen fuel cells would be wonderful for the environment. They combine hydrogen with oxygen from the atmosphere to produce electricity, and they emit pure water. The hydrogen can be made by electrolysis of water, and the energy for the electrolysis can be provided by renewable energy such as solar and wind. Though hydrogen must be stored at high pressures or low temperatures, it can be transported and used to replace fossil fuels in most of their applications. Then why are the fossil fuel companies so eager to transition to a hydrogen economy? They now are applying for grants from stimulus money for research on hydrogen power. There must be more to the story and that is where magic comes in.

It would take a tremendous amount of magic to make hydrogen a viable source of energy within 30 years. Currently, 95% of commercial hydrogen is made from fossil fuels, primarily methane. Producing hydrogen from methane is energy intensive. It requires that methane be reacted with steam-heated to about 1100°C. That reaction produces hydrogen and carbon monoxide – which is then treated with additional steam at 380°C to convert the carbon monoxide to carbon dioxide. Not only is carbon dioxide produced as a byproduct, but it takes a tremendous amount of fossil fuel to heat the steam hot enough to carry out the reaction. Hydrogen produced in this way is called Brown hydrogen, because of all the fossil fuels used. You’re probably beginning to see why fossil fuel companies are so eager to transition to a hydrogen economy.

But wait. All we would need to do is capture the carbon dioxide produced in making Brown hydrogen and store it underground. Hydrogen could then be produced without adding more CO2 to the atmosphere, so it is called Blue hydrogen. Fossil fuel companies are now pursuing grants and subsidies to develop Carbon Capture and Storage Systems (CSS) to do just that. But there are a few problems. Fossil fuel companies knew as far back as 1979 (see memo below) that adding more CO2 to the atmosphere would cause global warming and damage the environment. A CSS system requires little new technology, so why did they not develop CSS then – and global warming would never have become a problem. Fossil fuel companies did not do it because it would have made their products more expensive, and demand would have gone down. And they are even less serious about developing CSS systems now. With prices dropping on renewable technologies and energy storage systems, CSS would make carbon or hydrogen fuels so expensive that it would accelerate the transmission to renewable energy and battery storage.

Though there are currently large supplies of methane available from fracking operations, using fracked methane to produce hydrogen just isn’t a good idea. The main problems associated with fracking are methane leaks and earthquakes (caused by the disposal of fracking fluids). It has been estimated that about 20% of the methane produced at the wellhead is lost through transmission losses and leaks. Because so much methane is lost during production, France has recently prohibited American fracked methane from being sold there. Though the amount of methane in the atmosphere is small, methane is 72 times more potent as a greenhouse gas than carbon dioxide. As the graph below shows, the methane concentration in the atmosphere has grown exponentially – and it now accounts for about 1/4 as much global warming as carbon dioxide.

That brings us to hydrogen produced by electrolysis, called Green hydrogen. To create the infrastructure to produce enough Green hydrogen to transition to a hydrogen economy would take more than 30 years. To get there, we would have to start now. That would require Black and Brown hydrogen to be used while we develop a CSS system, and then Blue hydrogen could be used until we have a fully operational Green hydrogen infrastructure. We would be dependent on fossil fuels for at least 30 more years, and the concentration of carbon dioxide in the atmosphere would certainly go up. The best carbon capture systems are trees, oceans, and soils (through regenerative agriculture). Currently, those systems have not been able to keep up. Deforestation, commercial farming, and the acidification of the oceans are exhausting those systems’ abilities to capture CO2. The environment of the Earth cannot absorb much more carbon dioxide, and we certainly can’t wait 30 years on the chance that a commercial scale CSS system will be developed.

Hydrogen is very useful for things such as welding, food processing, ammonia production, and rocket fuel – but it will never be useful to power our economy. That is because a hydrogen economy would be terribly energy inefficient. If you were to use electricity from wind to produce hydrogen, transport the hydrogen to where it is needed, and use hydrogen fuel cells to power your car, about two-thirds of the energy would be lost in the process. The electrical energy that would take you 300 miles in a battery-powered car, would only take you 100 miles in a hydrogen-powered car. There is also no infrastructure in place to conveniently transport large volumes of hydrogen. Natural gas pipelines could not be used, as hydrogen reacts with metals and makes them brittle. I contrast, transmission lines for electricity are already in place and, if upgraded to handle the larger load, they could deliver power directly to your home and your car – and do it three times more efficiently.

Finally, hydrogen is explosive. If you have ever seen a hydrogen filled balloon exploded, you are probably aware of the tremendous power of a hydrogen explosion. Hydrogen explosions are rare, but are bound to happen if hydrogen were in wide use. A hydrogen explosion occurred in an AT&T Uninterruptible Power Source battery room in 2020. The explosion blew a 400 square foot hole in the roof and collapsed walls and ceilings throughout a large portion of the 50,000 square foot building. Fortunately, the computer/data center was vacant at the time and there were no injuries.

All things considered, unless you own a fossil fuel company or believe in magic, trying to convert to a hydrogen economy is a really bad idea. 

© 2021 – J. C. Moore. All rights reserved.

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Greenhouse gases play a huge role in keeping the surface of the Earth warm. Without the greenhouse effect, the temperature of the Earth would average about -18°C, and all the water on the Earth’s surface would be ice. The average temperature of the Earth’s surface is now about 15°C and rising. The graph below shows the concentration of the main greenhouse gases in the Earth’s atmosphere, and how they have changed in the last two millennia. 

Inarguably, an increase in the greenhouse gas concentrations will warm the Earth – and we are seeing that happen. The average temperature of the Earth is now 1.2°F warmer than it was in 1850. The temperature of the Earth was fairly constant over the thousand years before the industrial age, and people, plants, animals, and our agricultural practices have adapted to that temperature. What will happen as the Earth’s temperature rises? We are finding out, and the effects are alarming.

Of the greenhouse gases, water accounts for about 70% of the greenhouse effect, carbon dioxide about 20%, methane 4%, nitrous oxide 1%, and the other greenhouse gases together about 5%. Our efforts to reduce global warming have focused mostly on carbon dioxide, as its concentration has increased over 40% from our use of fossil fuels. It will take time to phase out fossil fuels and transition to the use of renewable energy. The concentration of methane has grown appreciably in the last century, from about 800 parts per billion (ppb) to over 1900 ppb and it is rising rapidly. Methane has about an eight year half-life in the atmosphere before it is converted to carbon dioxide by natural process. The methane in the atmosphere would decrease quickly if we stopped putting it there. That is important, as methane has about 72 times the global warming potential of carbon dioxide.

The main cause of the rise in methane is commercial leaks, oil production, and fracking operations. In commercial sales, it is sometimes less expensive to ignore small leaks than to fix them. But many small leaks add up and it has been estimated that about 10% of natural gas put into pipelines is lost before it reaches the end user. Some of those problems could be fixed. Methane is also produced as a byproduct of oil production. If the amount of gas is too small to be sold commercially, it is often flared, i.e., lit like a torch. That converts it into carbon dioxide, which is less damaging to the environment. 

Fracking operations now produce a tremendous amount of natural gas for commercial use, and considerable amounts of methane escape into the atmosphere from the drilling operations and pipeline leaks. It requires effort and resources to contain the methane at the wellhead and to fix storage and transmission leaks. The EPA requires that leaks be self-reported, but often they were just ignored. Just recently, it has become possible to detect methane from GHGSat satellites. Below is a map that shows eight leaks in a 25 mi.² area in Turkmenistan, as they were seen by satellite. Estimates were that those leaks accounted for about 10,000 kg of methane a day. The methane was from fracking operations, pipeline leaks, and unlit flares.

Before satellites, most methane emissions were discovered by infrared cameras. Using them, it was found that the methane emissions from the Permian basin in Texas and New Mexico were much greater than those reported. Much of that came from unlit flares, which could easily be corrected. One accident at a gas well in Ohio is now thought to be the largest methane leak ever in the United States. Three different oil and gas facilities in Algeria were found to be leaking methane amounts equivalent to the carbon dioxide produced by a medium-size coal-fired power plant. The detection of leaks has been spotty and regulation of leaks has been difficult in the past. There is considerable economic incentive for gas companies to reduce methane emissions from leaks. However, it is expensive to send out crews to detect and repair smaller leaks, and many companies have just let them go.

The EPA expects the oil and gas industry to self-report and to repair leaks, but many companies just don’t. There are plans to deploy seven more GHGSat satellites to monitor greenhouse gas emissions. With them, it will be possible to detect and enforce the regulation of many methane leaks. It has been estimated that cutting methane emissions by 40% would have the same effect as taking 60% of the world’s coal-fired power plants off-line. And, we could easily cut methane emissions by 40% within the next decade.

(C) 2021 J.C. Moore All rights reserved.